The key fits and turns to unlock right? Do you see it unlocked looking in?
I am guessing that the resistance you are facing is due to the window not automatically lowering a little which it normally would do when you open the door if battery was alive.
You should be able to just tug the door a little harder but carefully to force it open without damaging window.
After you get in, pop the hood to hook up charger as the trunk will not open if you don't have power.
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